Synthesis and optimization of high-performance amine-based polymer for CO2 separation
Separation Science and Engineering|Updated:2026-01-06
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Synthesis and optimization of high-performance amine-based polymer for CO2 separation
Chinese Journal of Chemical EngineeringVol. 50, Issue 10, Pages: 168-176(2022)
Affiliations:
1. Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University,Tianjin,China,300350
2. Tianjin Key Laboratory of Membrane Science and Desalination Technology, State Key Laboratory of Chemical Engineering, Collaborative Innovation Center of Chemical Science and Engineering, Haihe Laboratory of Sustainable Chemical Transformations, Tianjin University,Tianjin,China,300350
3. College of Chemical Engineering and Safety, Binzhou University, Engineering Research Center for Industrial Wastewater Treatment and Reuse of Shandong Province,Binzhou,China,256600
Membrane technology features inspiring excellence from numerous separation technologies for CO
2
capture from post-combustion gas. Polyvinylamine (PVAm)-based facilitated transport membranes show significantly high separation performance
which has been proven promising for industrial scale-up. However
commercialized PVAm with low molecular weight and excessive crystallinity is not available to prepare high-performance membranes. Herein
the synthesis process of PVAm was optimized by regulating polymerization and acidic hydrolytic conditions. The membranes based on PVAm with a molecular weight of 154 kDa and crystallinity of 11.37% display high CO
2
permeance of 726 GPU and CO
2
/N
2
selectivity of 55 at a feed gas pressure of 0.50 MPa. Furthermore
we established a PVAm synthesis reactor with an annual PVAm solution (1%(mass)) capacity of over 7000 kg and realized the scaled-up manufacture of both PVAm and composite membranes.
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Related Author
Zhi Wang
Jixiao Wang
Bo Wang
Ye Yuan
Menglong Sheng
Wenyan Feng
Haoqing Xu
Tae-Hyun Bae
Related Institution
Tianjin Key Laboratory of Membrane Science and Desalination Technology, State Key Laboratory of Chemical Engineering, Collaborative Innovation Center of Chemical Science and Engineering, Tianjin University
Life and Health Research Institute, School of Chemistry and Chemical Engineering, Tianjin University of Technology
2 Nanyang Environment and Water Research Institute, Interdisciplinary Graduate School, Nanyang Technological University
3 School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive
4 School of Civil and Environmental Engineering, Nanyang Technological University, 50 Nanyang Avenue