Enhancement of acetylene and ethylene yields in partially decoupled oxidation of ethane by changing the composition of heat carrier
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Enhancement of acetylene and ethylene yields in partially decoupled oxidation of ethane by changing the composition of heat carrier
Chinese Journal of Chemical EngineeringVol. 47, Issue 7, Pages: 71-78(2022)
Affiliations:
Beijing Key Laboratory of Green Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University,Beijing,China,100084
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Published:2022
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Tianpeng LiZhou, Jiajia Luo, Tiefeng Wang. Enhancement of acetylene and ethylene yields in partially decoupled oxidation of ethane by changing the composition of heat carrier[J]. Chinese Journal of Chemical Engineering, 2022, 47(7): 71-78.
DOI:
Tianpeng LiZhou, Jiajia Luo, Tiefeng Wang. Enhancement of acetylene and ethylene yields in partially decoupled oxidation of ethane by changing the composition of heat carrier[J]. Chinese Journal of Chemical Engineering, 2022, 47(7): 71-78.DOI:
Enhancement of acetylene and ethylene yields in partially decoupled oxidation of ethane by changing the composition of heat carrier
a partially decoupled process (PDP) was proposed for efficient conversion of ethane to increase the ethylene yield and a new structural reactor called forward-impinging-back reactor (FIB) was proposed for scale-up. In this work
the influence of changing the composition and temperature of the heat carrier was investigated by simulations with detailed chemistry to further increase of the C
2
(C
2
H
2
+ C
2
H
4
) yield in the PDP of ethane. At ideal mixing conditions
the C
2
yield is 75.3% without steam addition and it is 82.9% at steam addition ratio of
β
=1.4. In comparison
the C
2
yield in an FIB reactor is 62.4% without steam addition and it increases to 78.5% with steam addition (
β
=1.4). The requirement of high mixing efficiency is diminished by steam addition
which is favorable for reactor scale-up.
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