Basic organic chemicals and high value–added products are mainly produced by hydrocarbon nitridation and oxidation. However

several drawbacks limit the application of the traditional oxidation and nitridation technologies in the future

such as complex processes

poor intrinsic safety

low atom utilization

and serious environmental pollution. The green nitridation and oxidation technologies are urgently needed. Hydrogen peroxide

a well–known green oxidant

is widely used in green hydrocarbon oxidation and nitridation. But its industrial production in China adopts fixed–bed technology

which is fall behind slurry–bed technology adopted by advanced foreign chemical companies

limiting the development of hydrogen peroxide industry and green hydrocarbon nitridation or oxidation industry. This article reviews the industrial production technologies of hydrogen peroxide and basic organic chemicals such as caprolactam

aniline

propene oxide

epichlorohydrin

phenol

and benzenediol

especially introduces the green production technologies of basic organic chemicals related with H

2

O

2

. The article also emphasis on the efforts of Chinese researchers in developing its own slurry–bed technology of hydrogen peroxide production

and corresponding green

hydrocarbon nitridation or oxidation technologies with hydrogen peroxide. Compared with traditional nitridation or oxidation technologies

green production technologies of caprolactam

propene oxide

epichlorohydrin

and benzenediol with hydrogen peroxide promote the nitrogen atom utilization from 60% to near 100% and the carbon atom utilization from 80% to near 100%. The waste emissions and environmental investments are reduced dramatically. Technological blockade against the green chemical industry of China are partially broken down

and technological upgrade in the chemical industry of China is guaranteed.