Investigation of the methane hydrate surface area during depressurization-induced dissociation in hydrate-bearing porous media
Energy, Resources and Environmental Technology|Updated:2026-01-06
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Investigation of the methane hydrate surface area during depressurization-induced dissociation in hydrate-bearing porous media
Chinese Journal of Chemical EngineeringVol. 32, Issue 4, Pages: 324-334(2021)
Affiliations:
1. Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences,Guangzhou,China,510640
2. CAS Key Laboratory of Gas Hydrate,Guangzhou,China,510640
3. Guangzhou Center for Gas Hydrate Research, Chinese Academy of Sciences,Guangzhou,China,510640
4. Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development,Guangzhou,China,510640
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Published:2021
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Xuke Ruan, Xiao-Sen Li. Investigation of the methane hydrate surface area during depressurization-induced dissociation in hydrate-bearing porous media[J]. Chinese Journal of Chemical Engineering, 2021, 32(4): 324-334.
DOI:
Xuke Ruan, Xiao-Sen Li. Investigation of the methane hydrate surface area during depressurization-induced dissociation in hydrate-bearing porous media[J]. Chinese Journal of Chemical Engineering, 2021, 32(4): 324-334.DOI:
Investigation of the methane hydrate surface area during depressurization-induced dissociation in hydrate-bearing porous media
The surface area of hydrate during dissociation in porous media is essentially important for the kinetics of hydrate dissociation. In this study
the methane hydrate surface area was investigated by the comparison results of experiments and numerical simulations during hydrate decomposition in porous media. The experiments of methane hydrate depressurization-induced dissociation were performed in a 1D high pressure cell filled with glass beads
an improved and valid 1D core-scale numerical model was developed to simulate gas production. Two conceptual models for hydrate dissociation surface area were proposed based on the morphology of hydrate in porous media
which formed the functional form of the hydrate dissociation surface area with porosity
hydrate saturation and the average radius of sand sediment particles. With the establishment of numerical model for depressurization-induced hydrate dissociation in porous media
the cumulative gas productions were modeling and compared with the experimental data at the different hydrate saturations. The results indicated that the proposed prediction equations are valid for the hydrate dissociation surface area
and the grain-coating surface area model performs well at lower hydrate saturation for hydrate dissociation simulation
whereas at higher hydrate saturation
the hydrate dissociation simulation from the pore-filling surface area model is more reasonable. Finally
the sensitivity analysis showed that the hydrate dissociation surface area has a significant impact on the cumulative gas production.
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