Insight into solute-solute and solute-solvent interactions of semicarbazide hydrochloride in water and D-glucose/D-sucrose+water solutions at temperatures (293.15 to 318.15) K

Ankita; Dinesh Chand; Anil Kumar Nain

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Insight into solute-solute and solute-solvent interactions of semicarbazide hydrochloride in water and D-glucose/D-sucrose+water solutions at temperatures (293.15 to 318.15) K

Chemical Engineering Thermodynamics | Updated：2026-01-06

- Insight into solute-solute and solute-solvent interactions of semicarbazide hydrochloride in water and D-glucose/D-sucrose+water solutions at temperatures (293.15 to 318.15) K
- Chinese Journal of Chemical Engineering Vol. 28, Issue 12, Pages: 3086-3095(2020)
- Affiliations：
  
  1. Department of Chemistry, Dyal Singh College, University of Delhi,New Delhi,India,110003
  2. Department of Chemistry, University of Delhi, Delhi,India,110007
  3. Department of Chemistry, Amity University Dubai Campus, Dubai International Academic City, Dubai, UAE
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：2020
- Accepted：
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Ankita, Dinesh Chand, Anil Kumar Nain. Insight into solute-solute and solute-solvent interactions of semicarbazide hydrochloride in water and D-glucose/D-sucrose+water solutions at temperatures (293.15 to 318.15) K[J]. Chinese Journal of Chemical Engineering, 2020, 28(12): 3086-3095.
DOI：

Ankita, Dinesh Chand, Anil Kumar Nain. Insight into solute-solute and solute-solvent interactions of semicarbazide hydrochloride in water and D-glucose/D-sucrose+water solutions at temperatures (293.15 to 318.15) K[J]. Chinese Journal of Chemical Engineering, 2020, 28(12): 3086-3095. DOI：

摘要

Abstract

The solute-solute and solute-solvent interactions of drug semicarbazide hydrochloride with carbohydrates (D-glucose/D-sucrose) are investigated by using volumetric

viscometric and acoustic properties. The measurements of the densities

ultrasonic speeds

and viscosities

. of semicarbazide hydrochloride in 5% and 10% D-glucose/D-sucrose+water (w/w) solutions were carried out at temperatures (293.15-318.15) K and at pressure

=101 kPa. The apparent molar volumes

limiting apparent molar volumes

apparent molar compressibilities

limiting apparent molar compressibilities

partial molar expansibilities

transfer volumes

° and transfer compressibilities

° have been calculated from the experimental data. The viscosity data were examined by using the Jones-Dole equation and the viscosity

and

coefficients were evaluated. The results are discussed in terms o

f solute-solute and solute-solvent interactions in these solutions. The structure making/breaking ability of semicarbazide hydrochloride is examined using the sign of temperature derivative of

-coefficient

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