Catalytic ozonation of volatile organic compounds (ethyl acetate) at normal temperature
Catalysis, Kinetics and Reaction Engineering|Updated:2026-01-06
|
Catalytic ozonation of volatile organic compounds (ethyl acetate) at normal temperature
Chinese Journal of Chemical EngineeringVol. 32, Issue 4, Pages: 159-167(2021)
Affiliations:
1. School of Environmental Science and Engineering, Tianjin University,Tianjin,China,300072
2. School of Chemical Engineering and Technology, Tianjin University,Tianjin,China,300072
3. Tianjin Key Laboratory of Indoor Air Environmental Quality Control, School of Environmental Science and Engineering, Tianjin University,Tianjin,China,300072
Author bio:
Funds:
DOI:
CLC:
Published:2021
Accepted:
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Jiahao Cui, Shejiang Liu, Hua Xue, Xianqin Wang, Ziquan Hao, Rui Liu, Wei Shang, Dan Zhao, Hui Ding. Catalytic ozonation of volatile organic compounds (ethyl acetate) at normal temperature[J]. Chinese Journal of Chemical Engineering, 2021, 32(4): 159-167.
DOI:
Jiahao Cui, Shejiang Liu, Hua Xue, Xianqin Wang, Ziquan Hao, Rui Liu, Wei Shang, Dan Zhao, Hui Ding. Catalytic ozonation of volatile organic compounds (ethyl acetate) at normal temperature[J]. Chinese Journal of Chemical Engineering, 2021, 32(4): 159-167.DOI:
Catalytic ozonation of volatile organic compounds (ethyl acetate) at normal temperature
摘要
Abstract
Catalytic treatments of VOCs at normal temperature can greatly reduce the cost and temperature of processing
and improve the safety factor in line with the requirements of green chemistry. Activated carbon fiber (ACF) was pretreated with 10% H
2
SO
4
by single factor optimization to increase specific surface area and pore volume obviously. The catalytic ozonation performance of ACF loaded with Au
Ag
Pt and Pd noble metals on ethyl acetate was investigated and Pd/ACF was selected as the optimal catalyst which had certain stability. Pd is uniformly distributed on the surface of ACF
and Palladium mainly exists in the form of Pd
0
with a amount of Pd
+2
. The specific surface area of the catalysts gradually decreases as the loading increases. The activation energy of ethyl acetate calculated by Arrhenius equation is 113 kJ·mol
-1
. With 1% Pd loading and the concentration ratio of ozone to ethyl acetate is 3:1
catalytic ozonation performance is maximized and the conversion rate of ethyl acetate reached to 60% in 30-50℃ at 15
000-30
000 h
-1
.
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Constructing fast mass-transfer channels with efficient catalytic ozonation activity in 2D manganese dioxide membranes by intercalating Fe/Mn bimetallic MOF
Preparation of Mn-Ce oxide-loaded Al2O3 by citric acid-assisted impregnation for enhanced catalytic ozonation degradation of dye wastewater
Supported catalytic packing prepared from ceramic packing for reactive distillation of ethyl acetate
Investigation on catalytic distillation for ethyl acetate production with different catalytic packing structures
Aminolysis of ethyl acetate in continuous flow and its reaction kinetics
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