Perspective on synthesis of high-energy-density fuels: From petroleum to coal-based pathway

Chengxiang Shi; Jisheng Xu; Lun Pan; Xiangwen Zhang; Ji-Jun Zou

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Perspective on synthesis of high-energy-density fuels: From petroleum to coal-based pathway

Review | Updated：2026-01-06

- Perspective on synthesis of high-energy-density fuels: From petroleum to coal-based pathway
- Chinese Journal of Chemical Engineering Vol. 35, Issue 7, Pages: 83-91(2021)
- Affiliations：
  
  1. Key Laboratory for Green Chemical Technology of the Ministry of Education, School of Chemical Engineering and Technology, Tianjin University,Tianjin,China,300072
  2. Collaborative Innovative Center of Chemical Science and Engineering (Tianjin),Tianjin,China,300072
- Author bio：
- Funds：
- DOI：
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- Published：2021
- Accepted：
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Chengxiang Shi, Jisheng Xu, Lun Pan, Xiangwen Zhang, Ji-Jun Zou. Perspective on synthesis of high-energy-density fuels: From petroleum to coal-based pathway[J]. Chinese Journal of Chemical Engineering, 2021, 35(7): 83-91.
DOI：

Chengxiang Shi, Jisheng Xu, Lun Pan, Xiangwen Zhang, Ji-Jun Zou. Perspective on synthesis of high-energy-density fuels: From petroleum to coal-based pathway[J]. Chinese Journal of Chemical Engineering, 2021, 35(7): 83-91. DOI：

摘要

Abstract

High-energy-density (HED) fuel is specifically pivotal to improve the performance of volume-limited aircrafts. The widely used HED fuels composed of polycyclic hydrocarbons are mainly synthesized from petroleum feedstocks. In order to ensure abundant supply

alternative resources such as coal should be considered. Herein

we summarize the synthesis methods and properties of typical HED fuels by using petroleum-derived cyclopentadiene (CPD) as key feedstock through dimerization

cycloaddition

hydrogenation and isomerization/photoisomerization reactions

and then propose a blueprint for synthesizing HED fuels from coal. The method to produce CPD from coal is analyzed and feasibility is demonstrated according to theoretical calculations and reported results. This review provides a novel route for synthesis of HED fuels from coal.

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