Mathematical model for iron corrosion that eliminates chemical potential parameters
Materials and Product Engineering|Updated:2026-01-06
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Mathematical model for iron corrosion that eliminates chemical potential parameters
Chinese Journal of Chemical EngineeringVol. 28, Issue 2, Pages: 603-612(2020)
Affiliations:
1. Department of Chemical and Petroleum Engineering, Sharif University of Technology, P.O. Box 511365-1115, Tehran,Iran
2. Young Researchers and Elite Club, Shiraz Branch, Islamic Azad University, Shiraz,Iran
3. Department of Chemistry, Sharif University of Technology, P.O. Box 511365-1115, Tehran,Iran
4. DWA Energy Limited, Bassingham, Lincoln LNS 9JP, United Kingdom
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Published:2020
Accepted:
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Hadi Seddiqi, Ali Sadatshojaie, Behzad Vaferi, Ehsan Yahyazadeh, Afshin Salehi, David A. Wood. Mathematical model for iron corrosion that eliminates chemical potential parameters[J]. Chinese Journal of Chemical Engineering, 2020, 28(2): 603-612.
DOI:
Hadi Seddiqi, Ali Sadatshojaie, Behzad Vaferi, Ehsan Yahyazadeh, Afshin Salehi, David A. Wood. Mathematical model for iron corrosion that eliminates chemical potential parameters[J]. Chinese Journal of Chemical Engineering, 2020, 28(2): 603-612.DOI:
Mathematical model for iron corrosion that eliminates chemical potential parameters
Iron corrosion in acidic media is a natural phenomenon that converts elemental iron to a more chemically-stable form
i.e
. its oxide and hydroxide. In this study
the iron corrosion process is modeled as a completely implicit problem
solved by a novel finite difference model to provide insight into the ionic aspects of corrosion behavior. This new mathematical model eliminates the chemical potential parameters from the corrosion process equations
thereby reducing the need for experimental determination of chemical potentials. The eliminatedchemical-potential-parameters model predicts and quantifies key parameters (concentrations of conjugate base ion
iron (II) ion
hydrogen ion
anodic and cathodic potentials
and the electrical current density) associated with the iron corrosion process in acidic solutions. The rigorous derivation and novel application of the eliminated-chemical-potential-parameters model and its results provide new insights into the iron corrosion process. The present model is also applicable in any industrial process which is associated with metal corrosion. The model helps to guide the design of future corrosion resistant systems
and various experimental studies pertaining to
corrosion inhibition techniques.
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