Electric conductivity and electric convertibility of potassium acetate in water, ethanol, 2,2,2-trifluoroethanol, 2-propanol and their binary blends
Chemical Engineering Thermodynamics|Updated:2026-01-06
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Electric conductivity and electric convertibility of potassium acetate in water, ethanol, 2,2,2-trifluoroethanol, 2-propanol and their binary blends
Chinese Journal of Chemical EngineeringVol. 26, Issue 12, Pages: 2581-2591(2018)
Affiliations:
Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, School of Energy and Power Engineering, Dalian University of Technology,Dalian,China,116024
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Published:2018
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Xi Wu, Shiming Xu, Debing Wu, Huan Liu. Electric conductivity and electric convertibility of potassium acetate in water, ethanol, 2,2,2-trifluoroethanol, 2-propanol and their binary blends[J]. Chin.J.Chem.Eng., 2018, 26(12): 2581-2591.
DOI:
Xi Wu, Shiming Xu, Debing Wu, Huan Liu. Electric conductivity and electric convertibility of potassium acetate in water, ethanol, 2,2,2-trifluoroethanol, 2-propanol and their binary blends[J]. Chin.J.Chem.Eng., 2018, 26(12): 2581-2591.DOI:
Electric conductivity and electric convertibility of potassium acetate in water, ethanol, 2,2,2-trifluoroethanol, 2-propanol and their binary blends
Salinity gradient energy between the concentrated and diluted electrolyte solutions can be converted to electric energy by using reverse electrodialysis (RED) technology. Electrolyte solution is a vital factor that impacts the energy conversion efficiency. Potassium acetate (KAc) was chosen as solute
and water
ethanol
2
2
2-trifluoroethanol (TFE)
2-propanol (IPA) and several of their binary mixtures were selected as solvents. Electric conductivity of these solutions were measured under varying conditions. KAc was easily ionized in water and possessed the maximum electric conductivity
following by KAc-H
2
O-TFE and KAc-H
2
O-ethanol
and then KAc in pure TFE
ethanol
and IPA respectively. For electric convertibility of these solutions working in a RED power generation system
it was found that the KAc-H
2
O possessed the maximum power density
and the KAc-ethanol-H
2
O possessed the larger open circuit voltage than aqueous KAc solution under the same working condition. Besides
it was observed that both the electric conductivity and electric convertibility were significantly influenced by the concen
tration and temperature of solution. With the increasing of concentration
electric conductivity of these solutions increased firstly and then reached to the peak
but later it decreased. Solution temperature took a positive impact role to the electric conductivity. Electric conductivity of these solutions can be estimated by using a modified amplitude version of Gaussian peak function.
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