Experimental measurement and thermodynamic modeling of binary and ternary solid-liquid phase equilibrium for the systems formed by L-arabinose, D-xylose and water
Chemical Engineering Thermodynamics|Updated:2026-01-06
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Experimental measurement and thermodynamic modeling of binary and ternary solid-liquid phase equilibrium for the systems formed by L-arabinose, D-xylose and water
Chinese Journal of Chemical EngineeringVol. 25, Issue 10, Pages: 1467-1472(2017)
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College of Chemistry and Chemical Engineering, Ocean University of China,Qingdao,China,266100
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Published:2017
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Lei Guo, Lianying Wu, Weitao Zhang, Chen Liang, Yangdong Hu. Experimental measurement and thermodynamic modeling of binary and ternary solid-liquid phase equilibrium for the systems formed by L-arabinose, D-xylose and water[J]. , 2017, 25(10): 1467-1472.
DOI:
Lei Guo, Lianying Wu, Weitao Zhang, Chen Liang, Yangdong Hu. Experimental measurement and thermodynamic modeling of binary and ternary solid-liquid phase equilibrium for the systems formed by L-arabinose, D-xylose and water[J]. , 2017, 25(10): 1467-1472.DOI:
Experimental measurement and thermodynamic modeling of binary and ternary solid-liquid phase equilibrium for the systems formed by L-arabinose, D-xylose and water
Solid-liquid phase equilibrium data for binary (L-arabinose-water) and (D-xylose-water) systems at temperatures from (269.85-298.05) K and ternary (L-arabinose-D-xylose-water) system at temperatures of 273.85 K
278.85 K and 284.45 K were measured at atmospheric pressure. The ternary phase diagrams of the systems were constructed on the base of the measured solubility. Two pure solid phases were formed at given temperatures
including pure L-arabinose and pure D-xylose
which were confirmed and determined by the method of Schreinemakers' wet residue. At the same temperature
the crystallization region of L-arabinose was larger than D-xylose's. The acquired solubility data were then correlated using the NRTL model
Wilson model and Xu model. The calculated solubility with the three models agreed well with the experimental values.
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