This paper describes the application of ultrasound waves on hydrodynamics and mass transfer characteristics in the gas-liquid flow in a T-shape microreactor with a diameter of 800 μm. A 1.7 MHz piezoelectric transducer (PZT) was employed to induce the vibration in this microreactor. Liquid side volumetric mass transfer coefficients were measured by physical and chemical methods of CO

2

absorption into water and NaOH solution. The approach of absorption of CO

2

into a 1 mol·L

-1

NaOH solution was used for analysis of interfacial areas. With the help of a photography system

the fluid flow patterns inside the microreactor were analyzed. The effects of superficial liquid velocity

initial concentration of NaOH

superficial CO

2

gas velocity and length of microreactor on the mass transfer rate were investigated. The comparison between sonicated and plain microreactors (microreactor with and without ultrasound) shows that the ultrasound wave irradiation has a significant effect on

k

L

a

and interfacial area at various operational conditions. For the microreactor length of 12 cm

ultrasound waves improved

k

L

a

and interfacial area about 21% and 22%

respectively. From this study

it can be concluded that ultrasound wave irradiation in microreactor has a great effect on the mass transfer rate. This study suggests a new enhancement technique to establish high interfacial area and

k

L

a

in microreactors.