Highly selective synthesis for 4, 4'-bisphenol F from phenol and formaldehyde catalyzed with [C<sub>4</sub>mim][HSO<sub>4</sub>] ionic liquid

DanfengWang; Zhicheng He; Zhimin Wu; Ying Tan; Yongfei Li; Yuejin Liu

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Highly selective synthesis for 4, 4'-bisphenol F from phenol and formaldehyde catalyzed with [C₄mim][HSO₄] ionic liquid

Catalysis, Kinetics and Reaction Engineering | Updated：2026-01-06

- Highly selective synthesis for 4, 4'-bisphenol F from phenol and formaldehyde catalyzed with [C₄mim][HSO₄] ionic liquid
- Chinese Journal of Chemical Engineering Vol. 24, Issue 9, Pages: 1166-1170(2016)
- Affiliations：
  
  College of Chemical Engineering, Xiangtan University,Hunan,Xiangtan,China,411105
- Author bio：
- Funds：
- DOI：
  CLC： 10.1016/j.cjche.2016.02.005
- Published：2016
- Accepted：
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mim][HSO
DOI：

mim][HSO DOI：

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Abstract

The effects of N-methylimidazole cation[C

mim

]

with different alkyl chain lengths

the types of cations and anions of ionic liquids and the reaction parameters on the catalytic activity and the selectivity for 4

4'-bisphenol F were investigated. The hydrogen bonding between the hydroxyl of phenol and the C2-position hydrogen of imidazole moiety in hydrophilic imidazole-based ionic liquid has important influence on the selectivity for 4

4'-bisphenol F

and under the conditions of the molar ratio of phenol/[C

mim

]

[HSO

]

1:1

reaction temperature 65℃ and the theoretical molar ratio of phenol/formaldehyde 2:1

the selectivity for 4

4'-bisphenol F reached 69.1%. Compared with the high phenol/formaldehyde ratio reported in literatures

the low molar ratio of phenol/formaldehyde and the low reaction temperature can greatly reduce energy consumption

and has important significance for industrial application.

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Highly selective synthesis for 4, 4'-bisphenol F from phenol and formaldehyde catalyzed with [C4mim][HSO4] ionic liquid

DOI：

摘要

Abstract

关键词

Keywords

references

Highly selective synthesis for 4, 4'-bisphenol F from phenol and formaldehyde catalyzed with [C₄mim][HSO₄] ionic liquid