Measurement and modelization of VLE of binary mixtures of propyl acetate, butyl acetate or isobutyl acetate with methanol at pressure of 0.6 Mpa

P. Susial; D. García; R. Susial; Y. C. Clavijo; A. Martín

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Measurement and modelization of VLE of binary mixtures of propyl acetate, butyl acetate or isobutyl acetate with methanol at pressure of 0.6 Mpa

第25届中国过程控制会议专栏 | Updated：2026-01-06

- Measurement and modelization of VLE of binary mixtures of propyl acetate, butyl acetate or isobutyl acetate with methanol at pressure of 0.6 Mpa
- Chinese Journal of Chemical Engineering Vol. 24, Issue 5, Pages: 630-637(2016)
- Affiliations：
  
  2 Dept. Ingeniería Química y Tecnología del Medio Ambiente, Universidad de Valladolid,Valladolid,Spain,47071
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：2016
- Accepted：
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P. Susial, D. García, R. Susial, Y. C. Clavijo, A. Martín. Measurement and modelization of VLE of binary mixtures of propyl acetate, butyl acetate or isobutyl acetate with methanol at pressure of 0.6 Mpa[J]. Chin.J.Chem.Eng., 2016, 24(5): 630-637.
DOI：

P. Susial, D. García, R. Susial, Y. C. Clavijo, A. Martín. Measurement and modelization of VLE of binary mixtures of propyl acetate, butyl acetate or isobutyl acetate with methanol at pressure of 0.6 Mpa[J]. Chin.J.Chem.Eng., 2016, 24(5): 630-637. DOI：

摘要

Abstract

The vapor-liquid equilibriumof binarymixtures of propyl acetate

butyl acetate and isobutyl acetate withmethanol has been determined at a constant pressure of 0.6 MPa. Results have been modeledwith the Peng-Robinson equation

a traditional cubic equation of state widely employed in chemical industries

as well as with the perturbed-chain statistical associating fluid PC-SAFT theory of Gross-Sadowski. By correlation of the binary interaction parameters of these equations

the measured vapor-liquid equilibrium data can be accurately predicted. Thus

thiswork shows that thesemodels are able to represent the experimental data for systemswith associating compounds via hydrogen bonding.

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