Characteristics of Amine Surfactant Modified Peanut Shell and Its Sorption Property for Cr(Ⅵ)
分离科学与工程|Updated:2026-01-06
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Characteristics of Amine Surfactant Modified Peanut Shell and Its Sorption Property for Cr(Ⅵ)
Chinese Journal of Chemical EngineeringVol. 21, Issue 11, Pages: 1260-12681004-954160621-7(2013)
Affiliations:
1. 2 Postdoctoral Research Station of Power Engineering and Engineering Thermophysics, Shandong University,Jinan,China,250063
2. 3 Shandong Quality Inspection Center for Medical Devices,Jinan,China,250101
Author bio:
Funds:
DOI:
CLC:
Published:2013
Accepted:
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YUE Min, ZHANG Meng, LIU Bin, XU Xing, LI Xiaoming, YUE Qinyan, MA Chunyuan. Characteristics of Amine Surfactant Modified Peanut Shell and Its Sorption Property for Cr(Ⅵ)[J]. Chin.J.Chem.Eng., 2013, 21(11): 1260-1268.
DOI:
YUE Min, ZHANG Meng, LIU Bin, XU Xing, LI Xiaoming, YUE Qinyan, MA Chunyuan. Characteristics of Amine Surfactant Modified Peanut Shell and Its Sorption Property for Cr(Ⅵ)[J]. Chin.J.Chem.Eng., 2013, 21(11): 1260-1268.DOI:
Characteristics of Amine Surfactant Modified Peanut Shell and Its Sorption Property for Cr(Ⅵ)
摘要
Abstract
Modified peanut shell (MPS) was prepared by amination reaction with peanut shell (PS) as the starting material. The sorption of Cr(Ⅵ) oxyanions on MPS in static and column tests were investigated. In addition
the sorption isotherm and kinetic models were applied to confirm the sorption capacity and the sorption mechanisms. BET surface area analysis showed the physicochemical characteristics of the samples. The results of zeta potential
Fourier transform infrared (FT-IR) and Raman spectra analysis illustrated that chemical adsorption and ion exchange are the potential sorption mechanism. The static sorption test showed that the maximum sorption capacity (q
max
) of MPS for Cr(Ⅵ) increased with temperature
which indicated that the Cr(Ⅵ) sorption process was endothermic. The saturated sorption capacity of Cr(Ⅵ) in the column sorption test was 138.34 mg·g
-1
which accounted for 93.9% of the q
max
at 25 ℃. The regeneration capacity of MPS was evaluated using HCl solution as an eluent. The high regeneration efficiency (82.6%) validated the dominance of the ion exchange mechanism in the Cr(Ⅵ) sorption process with Cl
-
ions displacing Cr(Ⅵ) oxyanion on MPS. The Langmuir isotherm model showed a higher correlation
coefficient than the other adsorption isotherm models. And in the kinetic study
a pseudo-second-order model fit the data best.
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