Effect of the Para-substituent of the Tridentate Pyridine-based Ru(Ⅱ) Complex upon the Catalytic Activity in Transfer Hydrogenation

杨刚; 秦冬玲; 高宏飞; 徐南平

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Effect of the Para-substituent of the Tridentate Pyridine-based Ru(Ⅱ) Complex upon the Catalytic Activity in Transfer Hydrogenation

评述 | Updated：2026-01-06

- Effect of the Para-substituent of the Tridentate Pyridine-based Ru(Ⅱ) Complex upon the Catalytic Activity in Transfer Hydrogenation
- Chinese Journal of Chemical Engineering Vol. 19, Issue 1, Pages: 169-172(2011)
- Affiliations：
  
  State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology,Nanjing,China,10009
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：2011
- Accepted：
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-substituent of the Tridentate Pyridine-based Ru(Ⅱ) Complex upon the Catalytic Activity in Transfer Hydrogenation[J]. Chinese Journal of Chemical Engineering, 2011, 19(1): 169-172.
DOI：

-substituent of the Tridentate Pyridine-based Ru(Ⅱ) Complex upon the Catalytic Activity in Transfer Hydrogenation[J]. Chinese Journal of Chemical Engineering, 2011, 19(1): 169-172. DOI：

摘要

Abstract

Three stable 4-substituted pyridine-based ruthenium(Ⅱ)complexes[RuCl

(PPh

]

(L=4-R-2

6-bis (diethylaminomethylene)pyridine

R=Br

H or allyloxy)were synthesized.The catalytic activities of the complexes toward transfer hydrogenation from alcohols to ketones were investigated.The electronic effects of the para-substituent in the pyridyl ring were probed and we found that the electron-donating group increased the catalytic activity.The result suggests that an electron-donating group is probably preferential for linking the catalytic ruthenium complex and the chemically inert supporting molecules such as a carbosilane dendrimer.

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