Mathematical Modeling of the Oxidation of Polyunsaturated Fatty Acids in Emulsions with Stirring and Limited Oxygen Compensation
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Mathematical Modeling of the Oxidation of Polyunsaturated Fatty Acids in Emulsions with Stirring and Limited Oxygen Compensation
Chinese Journal of Chemical EngineeringVol. 16, Issue 2, Pages: 218-222(2008)
Affiliations:
1. State Key Laboratory of Food Science and Technology, Jiangnan University,Wuxi,China,214122
2. School of Food Science and Technology, Jiangnan University,Wuxi,China,214122
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Published:2008
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LÜ Bing, CHEN Jie, XIA Wenshui. Mathematical Modeling of the Oxidation of Polyunsaturated Fatty Acids in Emulsions with Stirring and Limited Oxygen Compensation[J]. , 2008, 16(2): 218-222.
DOI:
LÜ Bing, CHEN Jie, XIA Wenshui. Mathematical Modeling of the Oxidation of Polyunsaturated Fatty Acids in Emulsions with Stirring and Limited Oxygen Compensation[J]. , 2008, 16(2): 218-222.DOI:
Mathematical Modeling of the Oxidation of Polyunsaturated Fatty Acids in Emulsions with Stirring and Limited Oxygen Compensation
The oxidation of polyunsaturated fatty acids(PUFA)in emulsion with stirring and limited oxygen compensation was studied.A mathematical model of diffusion-oxidation was developed considering the mass transfer resistance of a gasliquid boundary
the resistance of the boundary layer from the emulsifier membrane
and the autocatalytictype autoxidation reaction of PUFA.The dynamic mass transfer coefficient of the emulsifier membrane
k
0
was introduced.The model was verified by comparing the predictions of the model with the experimental data.The results indicated that the model was in good agreement with the oxygen diffusion and linoleic acid oxidation in the emulsion
and showed good applicability in the prediction of the effect of the emulsifier type on the oxidation of PUFA in the emulsion.It indicated that the oxidation of PUFA in emulsions
with stirring and limited oxygen compensation from the atmosphere
was controlled mostly by mass transfer resistance from the emulsifier membrane.
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