Oxidation of Cyclohexane Catalyzed by TS-1 in Ionic Liquid with <i>Tert</i>-butyl-hydroperoxide

王建英; 赵华; 张向京; 刘润静; 胡永琪

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Oxidation of Cyclohexane Catalyzed by TS-1 in Ionic Liquid with Tert-butyl-hydroperoxide

Updated：2026-01-06

- Oxidation of Cyclohexane Catalyzed by TS-1 in Ionic Liquid with Tert-butyl-hydroperoxide
- Chinese Journal of Chemical Engineering Vol. 16, Issue 3, Pages: 373-375(2008)
- Affiliations：
  
  1. College of Chemical Engineering, Beijing Unversity of Chemical Technology,Beijing,China,100029
  2. College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology,Shijiazhuang,China,050018
- Author bio：
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- Published：2008
- Accepted：
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-butyl-hydroperoxide[J]. , 2008, 16(3): 373-375.
DOI：

-butyl-hydroperoxide[J]. , 2008, 16(3): 373-375. DOI：

摘要

Abstract

An efficient and environmentally friendly procedure was described for easy product isolation for the oxidation of cyclohexane with

Tert

-butyl-hydroperoxide catalyzed by titanium silicalite 1(TS-1)in ambient-temperature ionic liquid [emim

]

.Good yield and higher selectivity of products were found in the ionic liquid compared with in molecular solvent.The research results showed 13.2% conversion of cyclohexane

97.6% cyclohexanol and cyclohexanone selectivity were obtained in ionic liquid under mild conditions of 90℃.

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Oxidation of Cyclohexane Catalyzed by TS-1 in Ionic Liquid with Tert-butyl-hydroperoxide

DOI：

摘要

Abstract

关键词

Keywords

references