An innovative sol-gel method for preparing LiNi0.5Mn1.5O4 material with excellent electrochemical performance

Ma Jiarou; Li Jilan; Ma Fei; Qin Bingke

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An innovative sol-gel method for preparing LiNi_0.5Mn_1.5O₄ material with excellent electrochemical performance

Updated：2026-09-17

- An innovative sol-gel method for preparing LiNi_0.5Mn_1.5O₄ material with excellent electrochemical performance
- An innovative sol-gel method for preparing LiNi_0.5Mn_1.5O₄ material with excellent electrochemical performance
- 中国化学工程学报（英文） 2026年95卷第7期页码：361-374
- Affiliations：
  
  College of Environmental and Chemical Engineering, Dalian University, Dalian 116622, China
  School of Chemistry and Materials Engineering, Liupanshui Normal University, Liupanshui 553004, China
- Author bio：
  
  *Corresponding author. E-mail address:lihaiqing998@163.com(J. Li).
- Funds：
  
  We are thankful to the “Carbon Neutral Engineering Research Center of Guizhou colleges and universities in Coal Industry”(Qian Jiao Ji [2023] No. 044);“Guizhou Provincial Science and Technology Projects ”(Qiankehejichu-ZK [2022] Yiban531);“the High-level Talents Scientific Research Startup Foundation of Liupanshui Normal University(LPSSYKYJJ202006)
- DOI：
  中图分类号：
- 收稿：2025-11-26，
  
  修回：2026-02-09，
  
  录用：2026-02-10，
  
  网络首发：2026-03-07，
  
  纸质出版：2026-07
- Accepted：
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Ma Jiarou, Li Jilan, Ma Fei, 等. An innovative sol-gel method for preparing LiNi_0.5Mn_1.5O₄ material with excellent electrochemical performance[J]. 中国化学工程学报（英文）, 2026,95(7):361-374.

Ma Jiarou, Li Jilan, Ma Fei, et al. An innovative sol-gel method for preparing LiNi_0.5Mn_1.5O₄ material with excellent electrochemical performance[J]. Chinese Journal of Chemical Engineering, 2026, 95(7): 361-374.
Ma Jiarou, Li Jilan, Ma Fei, 等. An innovative sol-gel method for preparing LiNi_0.5Mn_1.5O₄ material with excellent electrochemical performance[J]. 中国化学工程学报（英文）, 2026,95(7):361-374. DOI：

Ma Jiarou, Li Jilan, Ma Fei, et al. An innovative sol-gel method for preparing LiNi_0.5Mn_1.5O₄ material with excellent electrochemical performance[J]. Chinese Journal of Chemical Engineering, 2026, 95(7): 361-374. DOI：

摘要

Abstract

The spinel-structured LiNi

0.5

1.5

(LNMO) has become one of the most promising cathode materials for next-generation high-energy-density lithium-ion batteries. However

the commercial application of LNMO remains challenging despite decades of research. To address the challenge

developing eco-friendly

cost-effective synthesis methods for high-performance LNMO materials is of critical importance. In this study

we developed an innovative sol-gel synthesis approach utilizing cost-effective and environmentally benign soluble starch as a chel

ating agent. Investigation into the effects of different calcination temperatures (700

800 and 900 ◦C) on LNMO materials revealed that the sample calcined at 800 ◦C for 3 h exhibited the best electrochemical performance. It delivered an initial discharge capacity of 136.88 mA·h·g

at 1 C

maintaining 95% of its initial capacity after 500 cycles. To the best of our knowledge

few studies have reported such excellent electrochemical performance in LNMO materials. Morphological and structural analyses revealed that the excellent electrochemical properties of the LNMO material primarily originated from its truncated octahedral morphology and disordered structure. These findings provide valuable insights into the development of LNMO materials with high-rate capability and long-cycle-life performance.

关键词

Keywords

references

G. Ganas, G. Kastrinaki, D. Zarvalis, G. Karagiannakis, A.G. Konstandopoulos, D. Versaci, S. Bodoardo, Synthesis and characterization of LNMO cathode materials for lithium-ion batteries, Mater. Today Proc. 5 (14) (2018) 27416—27424.

X.L. Cui, T.T. Geng, F.L. Zhang, N.S. Zhang, D.N. Zhao, C.L. Li, S.Y. Li, The influence of the voltage plateau on the coulombic efficiency and capacity degradation in LiNi 0.5 Mn 1.5 O 4 materials, J. Alloys Compd. 820 (2020) 153443.

T. Kocak, X.D. Qi, X.G. Zhang, Electrochemical performance of high voltage LiNi 0.5 Mn 1.5 O 4 based on environmentally friendly binders, Solid State Ion 383 (2022) 115989.

L. Balducci, H. Darjazi, E. Gonzalo, R. Cid, F. Bonilla, F. Nobili, Evaluation of electronic-ionic transport properties of a Mg/Zr-modified LiNi 0.5 Mn 1.5 O 4 cathode for Li-ion batteries, ACS Appl. Mater. Interfaces 15 (48) (2023) 55620—55632.

G. Courbaron, E. Petit, J. Serrano-Sevillano, C. Labrugeˋre-Sarroste, J. Olchowka, D. Carlier, N. Delpuech, C. Aymonier, L. Croguennec, Improved electrochemical performance for high-voltage spinel LiNi 0.5 Mn 1.5 O 4 modified by supercritical fluid chemical deposition, ACS Appl. Mater. Interfaces 15 (2) (2023) 2812—2824.

X.Y. Dai, A.J. Zhou, J. Xu, B. Yang, L.P. Wang, J.Z. Li, Superior electrochemical performance of LiCoO 2 electrodes enabled by conductive Al 2 O 3 -doped ZnO coating via magnetron sputtering, J. Power Sources 298 (2015) 114—122.

Z.F. Wang, X.Y. Dai, H.J. Chen, F.Z. Wu, Y. Mai, S.E. Li, Y.J. Gu, J.Z. Li, A.J. Zhou, Simultaneously constructing a TiO 2 —LiF composite coating enhancing the cycling stability of LiCoO 2 at 4.6 V high voltage, ACS Sustainable Chem. Eng. 10 (25) (2022) 8151—8161.

L. Britala, M. Marinaro, G. Kucinskis, A review of the degradation mechanisms of NCM cathodes and corresponding mitigation strategies, J. Energy Storage 73 (2023) 108875.

B. Li, D.G. Xia, Anionic redox in rechargeable lithium batteries, Adv. Mater. 29 (48) (2017) 1701054.

J. Akimoto, Y. Hamada, N. Ishida, Y. Idemoto, Y. Matsushita, K. Kataoka, Structural change and morphological surface degradation upon electrochemical Li extraction from a single crystal of spinel-type LiNi 0.5 Mn 1.5 O 4 , Cryst. Growth Des. 20 (7) (2020) 4533—4539.

W.L. Huang, L. Yan, L.L. Zhang, X.L. Zhang, Z. Wu, C.P. Zhu, Z. Fang, K. Yang, Bifunctional urea surface-modified high voltage LiNi 0.5 Mn 1.5 O 4 cathode for enhanced electrochemical performance, Electrochim. Acta 458 (2023) 142525.

X.L. Bi, L.J. Chang, S.Y. Cao, S.H. Luo, W. Yang, A.L. Wei, R.F. Yang, J.N. Liu, Preparation and improvement of electr ochemical performance of LiNi 0.5 Mn 1. 5 O 4 cathode materials in situ coated with AlPO 4 , Energy Fuels 37 (4) (2023) 3236—3246.

M. Wentker, M. Greenwood, J. Leker, A bottom-up approach to lithium-ion battery cost modeling with a focus on cathode active materials, Energies 12 (3) (2019) 504.

K. Ragavendran, X. Hui, X. Gu, D. Sherwood, B. Emmanuel, A.K. Arof, On the graphene incorporated LiMn 2 O 4 nano-structures: possibilities for tuning the preferred orientations and high rate capabilities, RSC Adv. 4 (104) (2014) 60106—60111.

I. Martens, N. Vostrov, M. Mirolo, M. Colalongo, P. Kúš, M.I. Richard, L.Z. Wang, X.B. Zhu, T.U. Schülli, J. Drnec, Revisiting phase transformation mechanisms in LiNi 0.5 Mn 1.5 O 4 high voltage cathodes with operando microdiffraction, ACS Materials Lett 4 (12) (2022) 2528—2536.

X.H. Liang, X.T. Jiang, S.B. Zeng, W. Xu, L.X. Lan, X. Wu, D.Y. Yang, SnO 2 oxide cathode coating: the key ingredient for bi-based polymer quasi-solid-state batteries, enabling stable cycling of high-voltage solid-state LiNi 0.5 Mn 1.5 O 4 /lithium metal battery, J. Electroanal. Chem. 913 (2022) 116280.

U. Nisar, R. Amin, R. Essehli, R.A. Shakoor, R. Kahraman, D.K. Kim, M.A. Khaleel, I. Belharouak, Extreme fast charging characteristics of zirconia modified LiNi 0.5 Mn 1.5 O 4 cathode for lithium ion batteries, J. Power Sources 396 (2018) 774—781.

Z.A. Qureshi, H.A. Tariq, H.M. Hafiz, R.A. Shakoor, S. AlQaradawi, R. Kahraman, Influence of graphene wrapped-cerium oxide coating on spherical LiNi 0. 5 Mn 1.5 O 4 particles as cathode in high-voltage lithium-ion batteries, J. Alloys Compd. 920 (2022) 165989.

J.M. Sun, P.T. Li, K. Wang, Y. Tan, B. Xue, J. Niu, Effect of Al 3+ and Al 2 O 3 comodification on electrochemical characteristics of the 5-V cathode material LiNi 0.5 Mn 1.5 O 4 , Ionics 26 (8) (2020) 3725—3736.

M.R. Laskar, D.H.K. Jackson, Y.X. Guan, S.Z. Xu, S.Y. Fang, M. Dreibelbis, M.K. Mahanthappa, D. Morgan, R.J. Hamers, T.F. Kuech, Atomic layer deposition of Al 2 O 3 -Ga 2 O 3 alloy coatings for Li[Ni 0.5 Mn 0.3 Co 0.2 ] O 2 cathode to improve rate performance in Li-ion battery, ACS Appl. Mater. Interfaces 8 (16) (2016) 10572—10580.

S.X. Deng, B.W. Xiao, B.Q. Wang, X. Li, K. Kaliyappan, Y. Zhao, A. Lushington, R. Y. Li, T.K. Sham, H. Wang, X.L. Sun, New insight into atomic-scale engineering of electrode surface for long-life and safe high voltage lithium ion cathodes, Nano Energy 38 (2017) 19—27.

J.H. Kim, S.T. Myung, Y.K. Sun, Molten salt synthesis of LiNi 0.5 Mn 1.5 O 4 spinel for 5 V class cathode material of Li-ion secondary battery, Electrochim. Acta 49 (2) (2004) 219—227.

L. Wen, Q. Lu, G.X. Xu, Molten salt synthesis of spherical LiNi 0.5 Mn 1.5 O 4 cathode materials, Electrochim. Acta 51 (21) (2006) 4388—4392.

E. McCalla, J.R. Dahn, The spinel and cubic rocksalt solid-solutions in the li—mn—ni oxide pseudo-ternary system, Solid State Ion 242 (2013) 1—9.

N. Kiziltas-Yavuz, M. Yavuz, S. Indris, N.N. Bramnik, M. Knapp, O. Dolotko, B. Das, H. Ehrenberg, A. Bhaskar, Enhancement of electrochemical performance by simultaneous substitution of Ni and Mn with Fe in Ni-Mn spinel cathodes for Li-ion batteries, J. Power Sources 327 (2016) 507—518.

P. Stüble, V. Mereacre, H. Geßwein, J.R. Binder, On the composition of LiNi 0. 5 Mn 1.5 O 4 cathode active materials, Adv. Energy Mater. 13 (10) (2023) 2203778.

H. Duncan, B. Hai, M. Leskes, C.P. Grey, G.Y. Chen, Relationships between Mn 3+ content, structural ordering, phase transformation, and kinetic properties in LiNi x Mn 2 — x O 4 cathode materials, Chem. Mater. 26 (18) (2014) 5374—5382.

H.B. Sun, A.Y. Hu, S. Spence, C.G. Kuai, D. Hou, L.Q. Mu, J. Liu, L.X. Li, C.J. Sun, S. Sainio, D. Nordlund, W. Luo, Y.H. Huang, F. Lin, Tailoring disordered/ordered phases to revisit the degradation mechanism of high-voltage LiNi 0. 5 Mn 1.5 O 4 spinel cathode materials, Adv. Funct. Mater. 32 (21) (2022) 2112279.

N. Amdouni, K. Zaghib, F. Gendron, A. Mauger, C.M. Julien, Structure and insertion properties of disordered and ordered LiNi 0.5 Mn 1.5 O 4 spinels prepared by wet chemistry, Ionics 12 (2) (2006) 117—126.

S.X. Deng, D.L. Mao, H. Wang, B. Wang, J.B. Liu, Y.L. Ma, H. Yan, Preparation and electrochemical properties of double-shell LiNi 0.5 Mn 1.5 O 4 hollow microspheres as cathode materials for Li-ion batteries, RSC Adv. 6 (51) (2016) 45369—45375.

J. Xiao, X.L. Chen, P.V. Sushko, M.L. Sushko, L. Kovarik, J.J. Feng, Z.Q. Deng, J.M. Zheng, G.L. Graff, Z.M. Nie, D. Choi, J. Liu, J.G. Zhang, M.S. Whittingham, High-performance LiNi 0.5 Mn 1.5 O 4 spinel controlled by Mn 3+ concentration and site disorder, Adv. Mater. 24 (16) (2012) 2109—2116.

A.Y. Chen, L.L. Kong, Y. Shu, W.C. Yan, W. Wu, Y.J. Xu, H.T. Gao, Y.C. Jin, Role of Al-doping with different sites upon the structure and electrochemical performance of spherical LiNi 0.5 Mn 1.5 O 4 cathode materials for lithium-ion batteries, RSC Adv. 9 (22) (2019) 12656—12666.

J. Jin, J.P. Wei, Z. Zhou, Z.J. Xie, Application of 5V spinel material LiNi 0.5 Mn 1. 5 O 4 in Li-ion batteries: single crystalline or polycrystalline, RSC Adv. 13 (18) (2023) 12394—12401.

T.C. Chen, H.M. Wu, D.F. Zhou, Y. Zhou, W. Yan, J.L. Song, J.B. Guo, The CeF 4 coated spinel LiNi 0.5 Mn 1.5 O 4 with improved electrochemical performance for 5V lithium-ion batteries, J. Mater. Sci. Mater. Electron. 33 (15) (2022) 11712—11724.

Y.L. Deng, J.R. Mou, L.H. He, F.Y. Xie, Q.J. Zheng, C.G. Xu, D.M. Lin, A core—s hell structured LiNi 0.5 Mn 1.5 O 4 @LiCoO 2 cathode material with superior rate capability and cycling performance, Dalton Trans. 47 (2) (2018) 367—375.

J.W. Wen, D.W. Zhang, Y. Zang, X. Sun, B. Cheng, C.X. Ding, Y. Yu, C.H. Chen, One-step synthesis and effect of heat-treatment on the structure and electrochemical properties of LiNi 0.5 Mn 1.5 O 4 cathode material for lithium-ion batteries, Electrochim. Acta 133 (2014) 515—521.

X.T. Li, Z.C. Shao, Y. Zhang, W. Zhang, H.M. Shao, A facile polymeric gel route synthesis of high-voltage LiNi 0.5 Mn 1.5 O 4 cathode material for lithium-ion batteries, Mater. Lett. 277 (2020) 128310.

V. Mereacre, P. Stüble, A. Ghamlouche, J.R. Binder, Enhancing the stability of LiNi(0.5)Mn(1.5)O(4) by coating with LiNbO(3) solid-state electrolyte: novel chemically activated coating process versus sol-gel method, Nanomaterials 11 (2) (2021) 548.

S. Patel, R. Kumar, S. Soni, A. Sodhiya, S. Patel, A.K. Singh, Synthesis and electrochemical investigation of lithium and cobalt dual-doped spinel LNMO nanomaterial as cathode for aqueous rechargeable lithium-ion battery, J. Mater. Sci. Mater. Electron. 33 (34) (2022) 25891—25906.

A.S. Rahim, N. Aziz, N.A.M. Nor, Z. Osman, LiNi 0.5 Mn 1.5 O 4 cathode material prepared by sol—gel method, Mol. Cryst. Liq. Cryst. 695 (1) (2019) 10—18.

L. Chladil, D. Kunický, T. Kazda, P. Vanýsek, O.Čech, P. Bača, In-situ XRD study of a Chromium doped LiNi 0.5 Mn 1.5 O 4 cathode for Li-ion battery, J. Energy Storage 41 (2021) 102907.

Y.Y. Luo, Z. Cui, C.X. Wu, B.S. Sa, C.L. Wen, H.Y. Li, J.P. Huang, C. Xu, Z.B. Xu, Enhanced electrochemical performance of a ti-cr-doped LiMn(1.5)Ni(0. 5)O(4) cathode material for lithium-ion batteries, ACS Omega 8 (25) (2023) 22721—22731.

Q. Chang, A.J. Wei, W. Li, X. Bai, L.H. Zhang, R. He, Z.F. Liu, Structural and electrochemical characteristics of Al 2 O 3 -modified LiNi 0.5 Mn 1.5 O 4 cathode materials for lithium-ion batteries, Ceram. Int. 45 (4) (2019) 5100—5110.

M.Y. Su, X.W. Dong, X.Y. Dai, B.B. Huang, M. Shen, T. Xu, Q.B. Liu, Accelerating phase evolution via a microwave sol-gel method improves the electrochemical performance of high-voltage spinel LiNi 0.5 Mn 1.5 O 4 cathode, J. Energy Storage 102 (2024) 114117.

K. Bi, S.X. Zhao, C. Huang, C.W. Nan, Improving low-temperature performance of spinel LiNi 0.5 Mn 1.5 O 4 electrode and LiNi 0.5 Mn 1.5 O 4 /Li 4 Ti 5 O 12 fullcell by coating solid-state electrolyte Li-Al-Ti-P-O, J. Power Sources 389 (2018) 240—248.

A. Bhatia, Y. Dridi Zrelli, J.P. Pereira-Ramos, R. Baddour-Hadjean, Detailed redox mechanism and self-discharge diagnostic of 4.9 V LiMn 1.5 Ni 0.5 O 4 spinel cathode revealed by Raman spectroscopy, J. Mater. Chem. A 9 (23) (2021) 13496—13505.

G. Oney, J.S. Sevillano, M. Ben Yahia, J. Olchowka, E. Suard, F. Weill, A. Demortieˋre, M.C. Cabanas, L. Croguennec, D. Carlier, Identification of degree of ordering in spinel LiNi 0.5 Mn 1.5 O 4 through NMR and Raman spectroscopies supported by theoretical calculations, Energy Storage Mater. 70 (2024) 103486.

L. Boulet-Roblin, C. Villevieille, P. Borel, C. Tessier, P. Novák, M. Ben Yahia, Versatile approach combining theoretical and experimental aspects of Raman spectroscopy to investigate battery materials: the case of the LiNi 0. 5 Mn 1.5 O 4 spinel, J. Phys. Chem. C 120 (30) (2016) 16377—16382.

Y. Xue, Z.B. Wang, F.D. Yu, Y. Zhang, G.P. Yin, Ethanol-assisted hydrothermal synthesis of LiNi 0.5 Mn 1.5 O 4 with excellent long-term cyclability at high rate for lithium-ion batteries, J. Mater. Chem. A 2 (12) (2014) 4185—4191.

K. Ariyoshi, Y. Iwakoshi, N. Nakayama, T. Ohzuku, Topotactic two-phase reactions of Li[Ni 1/2 Mn 3/2 ] O 4 (P4 3 32) in nonaqueous lithium cells, J. Electrochem. Soc. 151 (2) (2004) A296.

U. Nisar, F. Klein, C. Pfeifer, M. Wohlfahrt-Mehrens, M. Hölzle, P. Axmann, Elucidating the nature of secondary phases in LiNi 0.5 Mn 1.5 O 4 cathode materials using correlative Raman-SEM microscopy, Energy Storage Mater. 74 (2025) 103905.

A.J. Wei, W. Li, Q. Chang, X. Bai, R. He, L.H. Zhang, Z.F. Liu, Y.J. Wang, Effect of Mg 2+ /F- co-doping on electrochemical performance of LiNi 0.5 Mn 1.5 O 4 for 5 V lithium-ion batteries, Electrochim. Acta 323 (2019) 134692.

W.W. Wu, J.J. Chen, S. Cheng, H.F. Xiang, Preparation and electrochemical performance of spinel LiNi 0.5 - x Mn 1.5 + x O 4 (x = 0, 0.05, 0.1) hollow microspheres as cathode materials for lithium-ion batteries, Ionics 21 (7) (2015) 1843—1849.

J. Yoon, D. Kim, J.H. Um, M. Jeong, W. Oh, W.S. Yoon, Effect of local structural changes on rate capability of LiNi 0.5 Mn 1.5 O 4 - δ cathode material for lithium ion batteries, J. Alloys Compd. 686 (2016) 593—600.

Y.C. Jin, C.Y. Lin, J.G. Duh, Improving rate capability of high potential LiNi 0. 5 Mn 1.5 O 4 - x cathode materials via increasing oxygen non-stoichiometries, Electrochim. Acta 69 (2012) 45—50.

Z.J. Chen, R.R. Zhao, P. Du, H. Hu, T. Wang, L.C. Zhu, H.Y. Chen, Polyhedral LiNi 0.5 Mn 1.5 O 4 with excellent electrochemical properties for lithium-ion batteries, J. Mater. Chem. A 2 (32) (2014) 12835—12848.

S.Y. Li, J. Xie, D.N. Zhao, S. Geng, H.L. Li, C.L. Li, X.L. Cui, N.S. Zhang, Morphological evolution of spinel disordered LiNi 0.5 Mn 1.5 O 4 cathode materials for lithium-ion batteries by modified solid-state method, Ionics 25 (5) (2019) 1999—2006.

S. Ivanova, E. Zhecheva, R. Stoyanova, D. Nihtiano va, S. Wegner, P. Tzvetkova, S. Simova, High-voltage LiNi 1/2 Mn 3/2 O 4 spinel: cationic order and particle size distribution, J. Phys. Chem. C 115 (50) (2011) 25170—25182.

K.R. Chemelewski, E.S. Lee, W. Li, A. Manthiram, Factors influencing the electrochemical properties of high-voltage spinel cathodes: relative impact of morphology and cation ordering, Chem. Mater. 25 (14) (2013) 2890—2897.

H.L. Liu, M. Li, M.W. Xiang, J.M. Guo, H.L. Bai, W. Bai, X.F. Liu, Effects of crystal structure and plane orientation on lithium and nickel Co-doped spinel lithium manganese oxide for long cycle life lithium-ion batteries, J. Colloid Interface Sci. 585 (2021) 729—739.

S.F. Yang, J. Chen, Y.J. Liu, B.L. Yi, Preparing LiNi 0.5 Mn 1.5 O 4 nanoplates with superior properties in lithium-ion batteries using bimetal—organic coordination-polymers as precursors, J. Mater. Chem. A 2 (24) (2014) 9322—9330.

M. Shahabuddin, A.K. Wilson, A.C. Koech, N. Noginova, Probing charge transport kinetics in a plasmonic environment with cyclic voltammetry, ACS Omega 6 (50) (2021) 34294—34300.

Z.Q. Pei, J.W. Wang, H.F. Wang, K.X. Zheng, Q. Wang, J.X. Zhou, D.H. Ma, J. Lu, F.H. Lu, Morphological evolution and surface orientation effects of nickel manganese oxide in the preparation of LNMO cathode material, Electrochim. Acta 509 (2025) 145330.

Y.F. Deng, S.X. Zhao, Y.H. Xu, C.W. Nan, Effect of temperature of Li 2 O-—Al 2 O 3 —TiO 2 —P 2 O 5 solid-state electrolyte coating process on the performance of LiNi 0.5 Mn 1.5 O 4 cathode materials, J. Power Sources 296 (2015) 261—267.

C. Gao, H.P. Liu, S.F. Bi, Y.N. Wang, Q.E. Wang, S.S. Fan, X.H. Meng, Insights for the new function of N, N-dimethylpyrrolidone in preparation of a highvoltage spinel LiNi 0.5 Mn 1.5 O 4 cathode, ACS Appl. Mater. Interfaces 13 (17) (2021) 20014—20023.

X.J. Lu, C. Liu, W.J. Zhu, Z.P. Lu, W.L. Li, Y. Yang, G. Yang, Synthesis of micron-sized LiNi 0.5 Mn 1.5 O 4 single crystals through in situ microemulsion/coprecipitation and characterization of their electrochemical capabilities, Powder Technol. 343 (2019) 445—453.

X. Qin, J.J. Gong, J.L. Guo, B. Zong, M.S. Zhou, L. Wang, G.C. Liang, Synthesis and performance of LiNi 0.5 Mn 1.5 O 4 cathode materials with different particle morphologies and sizes for lithium-ion battery, J. Alloys Compd. 786 (2019) 240—249.

A.J. Wei, J.P. Mu, R. He, X. Bai, Z. Liu, L.H. Zhang, Y.J. Wang, Z.F. Liu, Enhancing electrochemical performance and structural stability of LiNi 0.5 Mn 1.5 O 4 cathode material for rechargeable lithium-ion batteries by boron doping, Ceram. Int. 47 (1) (2021) 226—237.

F.C. Lin, J.B. Guo, L.Y. Wang, Y. Zhou, H.M. Wu, D.F. Zhou, Synergistic effect of Mg and Y co-dopants on enhancement of electrochemical properties of LiNi 0. 5 Mn 1.5 O 4 spinel, Electrochim. Acta 399 (20 21) 139433.

B. Zong, Z.Y. Deng, S.H. Yan, Y.Q. Lang, J.J. Gong, J.L. Guo, L. Wang, G.C. Liang, Effects of Si doping on structural and electrochemical performance of LiNi 0. 5 Mn 1.5 O 4 cathode materials for lithium-ion batteries, Powder Technol. 364 (2020) 725—737.

B. Zong, Y.Q. Lang, S.H. Yan, Z.Y. Deng, J.J. Gong, J.L. Guo, L. Wang, G.C. Liang, Influence of Ti doping on microstructure and electrochemical performance of LiNi 0.5 Mn 1.5 O 4 cathode material for lithium-ion batteries, Mater. Today Commun. 24 (2020) 101003.

S.Y. Li, Y. Wei, P. Wang, Y.H. Feng, W.B. Liang, H. Ding, X.L. Cui, Synergism of Cu and Al co-doping on improvements of structural integrity and electrochemical performance for LiNi 0.5 Mn 1.5 O 4 , J. Alloys Compd. 820 (2020) 153140.

R.N. Zhu, S.J. Zhang, Q.X. Guo, Y. Zhou, J.T. Li, P.F. Wang, Z.L. Gong, More than just a protection layer: inducing chemical interaction between Li 3 BO 3 and LiNi0·5Mn1·5O 4 to achieve stable high-rate cycling cathode materials, Electrochim. Acta 342 (2020) 136074.

W.W. Sun, Y.J. Li, Y.M. Liu, Q.P. Guo, S.Q. Luo, J.G. Yang, C.M. Zheng, K. Xie, Hierarchical waxberry-like LiNi 0.5 Mn 1.5 O 4 as an advanced cathode material for lithium-ion batteries with a superior rate capability and long-term cyclability, J. Mater. Chem. A 6 (29) (2018) 14155—14161.

N. Yabuuchi, K. Yoshii, S.T. Myung, I. Nakai, S. Komaba, Detailed studi es of a high-capacity electrode material for rechargeable batteries, Li 2 MnO 3- LiCo(1/3)Ni(1/3)Mn(1/3)O 2 , J. Am. Chem. Soc. 133 (12) (2011) 4404—4419.

J. Lee, Y.W. Song, H. Lee, M.Y. Kim, J. Lim, Synthesis of high-voltage cathode material using the Taylor-Couette flow-based co-precipitation method, Front. Chem. 11 (2023) 1195170.

Z.A. Qureshi, M.E.S. Ali, R.A. Shakoor, S. AlQaradawi, R. Kahraman, Impact of synergistic interfacial modification on the electrochemical performance of LiNi 0.5 Mn 1.5 O 4 cathode materials, Ceram. Int. 50 (10) (2024) 17818—17835.

S.W. Sun, X.N. Li, C. Zhang, X.F. Wang, J.L. Wang, C. Wang, Z.J. Xu, Z.X. Cheng, Y. Bai, Magnetic field-induced disordered phase of spinel oxides for high battery performance, Adv. Mater. 36 (35) (2024) e2405876.

T.Y. Yang, K.N. Sun, Z.Y. Lei, N.Q. Zhang, Y. Lang, The influence of holding time on the performance of LiNi 0.5 Mn 1.5 O 4 cathode for lithium ion battery, J. Alloys Compd. 502 (1) (2010) 215—219.

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