SiO<sub>2</sub>-AlO(OH) composite-loaded gold nanoparticles catalyze the oxidative esterification reaction of 5-hydroxymethylfurfural

Zhang Hailin; Li Xianjie; Zhang Changcheng; Liu Yaping; Qiu Xiaomin; Xiao Meng; Huang Tingting; Zhu Quanhong; Shang Zhijie; Song Hongbing

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SiO₂-AlO(OH) composite-loaded gold nanoparticles catalyze the oxidative esterification reaction of 5-hydroxymethylfurfural

Updated：2026-09-17

- SiO₂-AlO(OH) composite-loaded gold nanoparticles catalyze the oxidative esterification reaction of 5-hydroxymethylfurfural
- SiO₂-AlO(OH) composite-loaded gold nanoparticles catalyze the oxidative esterification reaction of 5-hydroxymethylfurfural
- 中国化学工程学报（英文） 2026年95卷第7期页码：207-216
- Affiliations：
  
  College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
- Author bio：
  
  *Corresponding authors. E-mail addresses:shangzhijie1204@outlook.com(Z. Shang)
  *Corresponding authors. E-mail addresses:cehbsong@qust.edu.cn(H. Song).
- Funds：
  
  the National Natural Science Foundation of China(22378220)
- DOI：
  中图分类号：
- 收稿：2025-10-28，
  
  修回：2026-01-24，
  
  录用：2026-01-27，
  
  网络首发：2026-04-12，
  
  纸质出版：2026-07
- Accepted：
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Zhang Hailin, Li Xianjie, Zhang Changcheng, 等. SiO₂-AlO(OH) composite-loaded gold nanoparticles catalyze the oxidative esterification reaction of 5-hydroxymethylfurfural[J]. 中国化学工程学报（英文）, 2026,95(7):207-216.

Zhang Hailin, Li Xianjie, Zhang Changcheng, et al. SiO₂-AlO(OH) composite-loaded gold nanoparticles catalyze the oxidative esterification reaction of 5-hydroxymethylfurfural[J]. Chinese Journal of Chemical Engineering, 2026, 95(7): 207-216.
Zhang Hailin, Li Xianjie, Zhang Changcheng, 等. SiO₂-AlO(OH) composite-loaded gold nanoparticles catalyze the oxidative esterification reaction of 5-hydroxymethylfurfural[J]. 中国化学工程学报（英文）, 2026,95(7):207-216. DOI：

Zhang Hailin, Li Xianjie, Zhang Changcheng, et al. SiO₂-AlO(OH) composite-loaded gold nanoparticles catalyze the oxidative esterification reaction of 5-hydroxymethylfurfural[J]. Chinese Journal of Chemical Engineering, 2026, 95(7): 207-216. DOI：

摘要

Abstract

5-Hydroxymethylfurfural (HMF) is a highly valuable platform compound derived from cellulose

enabling the synthesis of various premium chemical products through oxidative esterification

including dimethyl 2

5-furanedicarboxylate (FDMC). This process finds widespread applications across numerous industries. By adjusting the Si/Al ratio

we prepared diverse catalyst carriers and utilized the urea precipitation method to fabricate various catalysts with a low gold loading of 1% (mass). These catalysts were subsequently characterized by a range of analytical techniques. Notably

the Au/SiO

-AlO(OH)-3 catalyst

characterized by its large specific surface area and abundant pore size

facilitated the highly dispersed presence of gold on the catalyst surface

exhibiting the best catalytic performance. Specifically

the Au/SiO

-AlO(OH)-3 catalyst demonstrated high efficiency

achieving 99.9% HMF conversion and 95.2% FDMC yield at a 0.25 mmol scale of HMF within 6 h under 0.1 equivalent Na

. This study proposes a mechanistic scheme for the conversion of HMF to FDMC

via

Au/SiO

-AlO(OH)-3-catalyzed oxidative esterification. Furthermore

free radical inhibition experiments were conducted

and the results indicated that superoxide anion radicals play a significant role in the HMF oxidativ

e esterification reaction. We also performed a series of substrate extensions

confirming the catalyst's excellent oxidative esterification effect on a wide range of substrates

including aromatic aldehydes and alcohols. These findings are expected to facilitate the development of oxidative esterification reactions of biomass-derived platform compounds.

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references

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SiO2-AlO(OH) composite-loaded gold nanoparticles catalyze the oxidative esterification reaction of 5-hydroxymethylfurfural

SiO2-AlO(OH) composite-loaded gold nanoparticles catalyze the oxidative esterification reaction of 5-hydroxymethylfurfural

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摘要

Abstract

关键词

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references

SiO₂-AlO(OH) composite-loaded gold nanoparticles catalyze the oxidative esterification reaction of 5-hydroxymethylfurfural

SiO₂-AlO(OH) composite-loaded gold nanoparticles catalyze the oxidative esterification reaction of 5-hydroxymethylfurfural