An innovative sol-gel method for preparing LiNi0.5Mn1.5O4 material with excellent electrochemical performance

Ma Jiarou; Li Jilan; Ma Fei; Qin Bingke

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An innovative sol-gel method for preparing LiNi_0.5Mn_1.5O₄ material with excellent electrochemical performance

Updated：2026-09-17

- An innovative sol-gel method for preparing LiNi_0.5Mn_1.5O₄ material with excellent electrochemical performance
- Chinese Journal of Chemical Engineering Vol. 95, Issue 7, Pages: 361-374(2026)
- Affiliations：
  
  College of Environmental and Chemical Engineering, Dalian University, Dalian 116622, China
  School of Chemistry and Materials Engineering, Liupanshui Normal University, Liupanshui 553004, China
- Author bio：
  
  *Corresponding author. E-mail address:lihaiqing998@163.com(J. Li).
- Funds：
- DOI：
  CLC：
- Received：26 November 2025，
  
  Revised：2026-02-09，
  
  Accepted：10 February 2026，
  
  Online First：07 March 2026，
  
  Published：2026-07
- Accepted：
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Ma Jiarou, Li Jilan, Ma Fei, et al. An innovative sol-gel method for preparing LiNi_0.5Mn_1.5O₄ material with excellent electrochemical performance[J]. Chinese Journal of Chemical Engineering, 2026, 95(7): 361-374.
DOI：

Ma Jiarou, Li Jilan, Ma Fei, et al. An innovative sol-gel method for preparing LiNi_0.5Mn_1.5O₄ material with excellent electrochemical performance[J]. Chinese Journal of Chemical Engineering, 2026, 95(7): 361-374. DOI：

摘要

Abstract

The spinel-structured LiNi

0.5

1.5

(LNMO) has become one of the most promising cathode materials for next-generation high-energy-density lithium-ion batteries. However

the commercial application of LNMO remains challenging despite decades of research. To address the challenge

developing eco-friendly

cost-effective synthesis methods for high-performance LNMO materials is of critical importance. In this study

we developed an innovative sol-gel synthesis approach utilizing cost-effective and environmentally benign soluble starch as a chel

ating agent. Investigation into the effects of different calcination temperatures (700

800 and 900 ◦C) on LNMO materials revealed that the sample calcined at 800 ◦C for 3 h exhibited the best electrochemical performance. It delivered an initial discharge capacity of 136.88 mA·h·g

at 1 C

maintaining 95% of its initial capacity after 500 cycles. To the best of our knowledge

few studies have reported such excellent electrochemical performance in LNMO materials. Morphological and structural analyses revealed that the excellent electrochemical properties of the LNMO material primarily originated from its truncated octahedral morphology and disordered structure. These findings provide valuable insights into the development of LNMO materials with high-rate capability and long-cycle-life performance.

关键词

Keywords

references

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