Abstract: The structural evolution of the chars frompyrolysis of biomass components (cellulose, hemicellulose and lignin) in a xenon lamp radiation reactor was investigated. The elemental composition analysis showed that the C content increased at the expense of H and O contents during the chars formation. The values of Δ_H/C/Δ_O/C for the formation of cellulose and hemicellulose chars were close to 2, indicating that dehydrationwas the dominant reaction. Meanwhile, the value was more than 3 for lignin char formation, suggesting that the occurrence of demethoxylation was prevalent. FTIR and XRD analyses further disclosed that the cellulose pyrolysis needed to break down the stable crystal structure prior to the severe depolymerization. As for hemicellulose and lignin pyrolysis, the weak branches and linkages decomposed firstly, followed by the major decomposition. After the devolatilization at the main pyrolysis stage, the three components encountered a slow carbonization process to form condensed aromatic chars. The SEM results showed that the three components underwent different devolatilization behaviors, which induced various surface morphologies of the chars.

Key words: Biomass components, Pyrolysis, Char, Structural characterization

摘要： The structural evolution of the chars frompyrolysis of biomass components (cellulose, hemicellulose and lignin) in a xenon lamp radiation reactor was investigated. The elemental composition analysis showed that the C content increased at the expense of H and O contents during the chars formation. The values of Δ_H/C/Δ_O/C for the formation of cellulose and hemicellulose chars were close to 2, indicating that dehydrationwas the dominant reaction. Meanwhile, the value was more than 3 for lignin char formation, suggesting that the occurrence of demethoxylation was prevalent. FTIR and XRD analyses further disclosed that the cellulose pyrolysis needed to break down the stable crystal structure prior to the severe depolymerization. As for hemicellulose and lignin pyrolysis, the weak branches and linkages decomposed firstly, followed by the major decomposition. After the devolatilization at the main pyrolysis stage, the three components encountered a slow carbonization process to form condensed aromatic chars. The SEM results showed that the three components underwent different devolatilization behaviors, which induced various surface morphologies of the chars.

关键词: Biomass components, Pyrolysis, Char, Structural characterization