SCI和EI收录∣中国化工学会会刊

›› 2017, Vol. 25 ›› Issue (9): 1256-1265.DOI: 10.1016/j.cjche.2016.11.018

• Chemical Engineering Thermodynamics • 上一篇    下一篇

The adsorption and corrosion inhibition of 8-hydroxy-7-quinolinecarboxaldehyde derivatives on C-steel surface in hydrochloric acid

A. M. Eldesoky1,2, S. G. Nozha3   

  1. 1 Engineering Chemistry Department, High Institute of Engineering & Technology, New Damietta, Egypt;
    2 Al-Qunfudah Center for Scientific Research(QCSR), Al-Qunfudah University College, Umm Al-Qura University, Saudi Arabia;
    3 Ministry of Health, Domyat Laboratory, Damietta, Egypt
  • 收稿日期:2016-07-06 修回日期:2016-11-19 出版日期:2017-09-28 发布日期:2017-10-11
  • 通讯作者: S. G. Nozha,E-mail:samar.nozha@gmail.com

The adsorption and corrosion inhibition of 8-hydroxy-7-quinolinecarboxaldehyde derivatives on C-steel surface in hydrochloric acid

A. M. Eldesoky1,2, S. G. Nozha3   

  1. 1 Engineering Chemistry Department, High Institute of Engineering & Technology, New Damietta, Egypt;
    2 Al-Qunfudah Center for Scientific Research(QCSR), Al-Qunfudah University College, Umm Al-Qura University, Saudi Arabia;
    3 Ministry of Health, Domyat Laboratory, Damietta, Egypt
  • Received:2016-07-06 Revised:2016-11-19 Online:2017-09-28 Published:2017-10-11

摘要: The protection influence of 8-hydroxy-7-quinolinecarboxaldehyde derivatives against C-steel corrosion was studied in 2 mol·L-1 HCl solutions at 30℃. Measurements were conducted under various experimental conditions using weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation (EFM) techniques. These studies have shown that 8-hydroxy-7-quinolinecarboxaldehyde derivatives are very good "green", mixed-type inhibitors. Corrosion rates obtained from both EFM and EIS methods are comparable with those recorded using Tafel extrapolation method, confirming validation of corrosion rates measured by the latter. The inhibitive action of these 8-hydroxy-7-quinolinecarboxaldehyde derivatives was discussed in terms of blocking the electrode surface by adsorption of the molecules through the active centers contained in their structures following Langmuir adsorption isotherm. Quantum chemical method was also employed to explore the relationship between the inhibitor molecular properties and its protection efficiency.

关键词: 8-Hydroxy-7-quinolinecarboxaldehyde, derivatives, C-steel, HCl, EFM

Abstract: The protection influence of 8-hydroxy-7-quinolinecarboxaldehyde derivatives against C-steel corrosion was studied in 2 mol·L-1 HCl solutions at 30℃. Measurements were conducted under various experimental conditions using weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation (EFM) techniques. These studies have shown that 8-hydroxy-7-quinolinecarboxaldehyde derivatives are very good "green", mixed-type inhibitors. Corrosion rates obtained from both EFM and EIS methods are comparable with those recorded using Tafel extrapolation method, confirming validation of corrosion rates measured by the latter. The inhibitive action of these 8-hydroxy-7-quinolinecarboxaldehyde derivatives was discussed in terms of blocking the electrode surface by adsorption of the molecules through the active centers contained in their structures following Langmuir adsorption isotherm. Quantum chemical method was also employed to explore the relationship between the inhibitor molecular properties and its protection efficiency.

Key words: 8-Hydroxy-7-quinolinecarboxaldehyde, derivatives, C-steel, HCl, EFM