Polymer/Ceramic Composite Membranes and Their Application in Pervaporation Process

摘要/Abstract

摘要： Pervaporation(PV),as an environmental friendly and energy-saving separation technology,has been received increasing attention in recent years.This article reviews the preparation and application of macroporous ceramic-supported polymer composite pervaporation membranes.The separation materials of polymer/ceramic composite membranes presented here include hydrophobic polydimethylsiloxane(PDMS) and hydrophilic poly(vinyl alcohol)(PVA),chitosan(CS) and polyelectrolytes.The effects of ceramic support treatment,polymer solution properties,interfacial adhesion and incorporating or blending modification on the membrane structure and PV performance are discussed.Two in-situ characterization methods developed for polymer/ceramic composite membranes are also covered in the discussion.The applications of these composite membranes in pervaporation process are summarized as well,which contain the bio-fuels recovery,gasoline desulfuration and PV coupled process using PDMS/ceramic composite membrane,and dehydration of alcohols and esters using ceramic-supported PVA or PVA-CS composite membrane.Finally,a brief conclusion remark on polymer/ceramic composite membranes is given and possible future research is outlined.

关键词: polymer/ceramic composite membrane, pervaporation, bio-fuel recovery, solvent dehydration, PV coupled process

Abstract: Pervaporation(PV),as an environmental friendly and energy-saving separation technology,has been received increasing attention in recent years.This article reviews the preparation and application of macroporous ceramic-supported polymer composite pervaporation membranes.The separation materials of polymer/ceramic composite membranes presented here include hydrophobic polydimethylsiloxane(PDMS) and hydrophilic poly(vinyl alcohol)(PVA),chitosan(CS) and polyelectrolytes.The effects of ceramic support treatment,polymer solution properties,interfacial adhesion and incorporating or blending modification on the membrane structure and PV performance are discussed.Two in-situ characterization methods developed for polymer/ceramic composite membranes are also covered in the discussion.The applications of these composite membranes in pervaporation process are summarized as well,which contain the bio-fuels recovery,gasoline desulfuration and PV coupled process using PDMS/ceramic composite membrane,and dehydration of alcohols and esters using ceramic-supported PVA or PVA-CS composite membrane.Finally,a brief conclusion remark on polymer/ceramic composite membranes is given and possible future research is outlined.

Key words: polymer/ceramic composite membrane, pervaporation, bio-fuel recovery, solvent dehydration, PV coupled process

中图分类号:

TQ028.8

刘公平, 卫旺, 金万勤, 徐南平. Polymer/Ceramic Composite Membranes and Their Application in Pervaporation Process[J]. , 2012, 20(1): 62-70.

LIU Gongping, WEI Wang, JIN Wanqin, XU Nanping. Polymer/Ceramic Composite Membranes and Their Application in Pervaporation Process[J]. , 2012, 20(1): 62-70.

参考文献

1 Lipnizki,F.,Hausmanns,S.,Ten,P.K.,Field,R.W.,Laufenberg,G.,"Organophilic pervaporation:Prospects and performance",Chem. Eng.J.,73,113-129(1999).
2 Shao,P.,Huang,R.Y.M.,"Polymeric membrane pervaporation",J. Membr.Sci.,287,162-179(2007).
3 Chapman,P.D.,Oliveira,T.,Livingston,A.G.,Li,K.,"Membranes for the dehydration of solvents by pervaporation",J.Membr.Sci.,318,5-37(2008).
4 Smitha,B.,Suhanya,D.,Sridhar,S.,Ramakrishna,M.,"Separation of organic-organic mixtures by pervaporation—A review",J.Membr. Sci.,241,1-21(2004).
5 Matsumoto,Y.,Sudoh,M.,Suzuki,Y.,"Preparation of composite UF membranes of sulfonated polysulfone coated on ceramics",J. Membr.Sci.,158,55-62(1999).
6 Peters,T.A.,Poeth,C.H.S.,Benes,N.E.,Buijs,H.C.W.M.,Vercauteren,F.F.,Keurentjes,J.T.F.,"Ceramic-supported thin PVA pervaporation membranes combining high flux and high selectivity; contradicting the flux-selectivity paradigm",J.Membr.Sci.,276,42-50(2006).
7 Yoshida,W.,Cohen,Y.,"Removal of methyl tert-butyl ether from water by pervaporation using ceramic-supported polymer membranes",J.Membr.Sci.,229,27-32(2004).
8 Xiangli,F.J.,Chen,Y.W.,Jin,W.Q.,Xu,N.P.,"Polydimethylsiloxane (PDMS)/ceramic composite membrane with high flux for pervaporation of ethanol-water mixtures",Ind.Eng.Chem.Res.,46,2224-2230(2007).
9 Zhu,Y.X.,Xia,S.S.,Liu,G.P.,Jin,W.Q.,"Preparation of ceramic-supported poly(vinyl alcohol)-chitosan composite membranes and their applications in pervaporation dehydration of organic/water mixtures",J.Membr.Sci.,349,341-348(2010).
10 Chen,Y.W.,Xiangli,F.J.,Jin,W.Q.,Xu,N.P.,"Organic-inorganic composite pervaporation membranes prepared by self-assembly of polyelectrolyte multilayers on macroporous ceramic supports",J. Membr.Sci.,302,78-86(2007).
11 Randon,J.,Paterson,R.,"Preliminary studies on the potential for gas separation by mesoporous ceramic oxide membranes surface modified by alkyl phosphonic acids",J.Membr.Sci.,134,219-223 (1997).
12 Peters,T.A.,Benes,N.E.,Keurentjes,J.T.F.,"Preparation of aberlystcoated pervaporation membranes and their application in the esterification of acetic acid and butanol",Appl.Catal.A,317,113-119 (2007).
13 Nova,C.J.M.,Paolucci-Jeanjean,D.,Belleville,M.P.,Barboiu,M.,Rivallin,M.,Rios,G.,"Elaboration,characterization and study of a new hybrid chitosan/ceramic membrane for affinity membrane chromatography",J.Membr.Sci.,321,81-89(2008).
14 Xiangli,F.J.,Wei,W.,Chen,Y.W.,Jin,W.Q.,Xu,N.P.,"Optimization of preparation conditions for polydimethylsiloxane(PDMS)/ ceramic composite pervaporation membranes using response surface methodology",J.Membr.Sci.,311,23-33(2008).
15 Wei,W.,Xia,S.S.,Liu,G.P.,Dong,X.L.,Jin,W.Q.,Xu,N.P.,"Effects of polydimethylsiloxane(PDMS)molecular weight on performance of PDMS/ceramic composite membranes",J.Membr.Sci.,375,334-344(2011).
16 Liu,G.P.,Xiangli,F.J.,Wei,W.,Liu,S.N.,Jin,W.Q.,"Improved performance of PDMS/ceramic composite pervaporation membranes by ZSM-5 homogeneously dispersed in PDMS via a surface graft/coating approach",Chem.Eng.J.,174,495-503(2011).
17 Wei,W.,Xia,S.S.,Liu,G.P.,Gu,X.H.,Jin,W.Q.,Xu,N.P.,"Interfacial adhesion between polymer separation layer and ceramic support for composite membrane",AIChE J.,56,1584-1592(2010).
18 Chen,Y.W.,Xiangli,F.J.,Jin,W.Q.,Xu,N.P.,"Streaming potential characterization of LBL membranes on porous ceramic supports",AIChE J.,53,969-977(2007).
19 Liu,G.P.,Hou,D.,Wei,W.,Xiangli,F.J.,Jin,W.Q.,"Pervaporation separation of butanol-water mixtures using polydimethylsiloxane/ceramic composite membrane",Chin.J.Chem.Eng.,19,40-44 (2011).
20 Xu,L.F.,Xiangli,F.J.,Chen,Y.W.,Jin,W.Q.,Xu,N.P.,"Influence of simulated ethanol fermentation components on pervaporation performance of PDMS/ceramic composite membranes",J.Chem.Ind. Eng.(China),58,1466-1472(2007).(in Chinese)
21 Hou,D.,Wei,W.,Xia,S.S.,Xiangli,F.J.,Chen,Y.W.,Jin,W.Q.,"Influence of inorganic salts on pervaporation performance of PDMS/ceramic composite membranes",J.Chem.Ind.Eng.(China),60,389-393(2009).(in Chinese)
22 Xu,R.,Liu,G.P.,Dong,X.L.,Jin,W.Q.,"Pervaporation separation of n-octane/thiophene mixtures using polydimethylsiloxane/ceramic composite membranes",Desalination,258,106-111(2010).
23 Xia,S.S.,Dong,X.L.,Zhu,Y.X.,Wei,W.,Xiangli,F.J.,Jin,W.Q.,"Dehydration of ethyl acetate-water mixtures using PVA/ceramic composite pervaporation membrane",Sep.Purif.Technol.,77,53-59(2011).
24 Xia,S.S.,Wei,W.,Liu,G.P.,Dong,X.L.,Jin,W.Q.,"Pervaporation properties of PVA/ceramic composite membrane for separation of ethyl acetate/ethanol/water ternary mixtures",Korean J.Chem.Eng.,DOI:10.1007/S11814-011-0154-X(2011).
25 Liu,G.P.,Wei,W.,Wu,H.,Dong,X.L.,Jiang,M.,Jin,W.Q.,"Pervaporation performance of PDMS/ceramic composite membrane in acetone butanol ethanol(ABE)fermentation-PV coupled process",J. Membr.Sci.,373,121-129(2011).
26 Li,W.X.,Zhang,X.J.,Xing,W.H.,Jin,W.Q.,Xu,N.P.,"Hydrolysis of ethyl lactate coupled by vapor permeation using polydimethylsiloxane/ceramic composite membrane",Ind.Eng.Chem.Res.,49,11244-11249(2010).
27 Kashiwagi,T.,Okabe,K.,Okita,K.,"Separation of ethanol from ethanol/water mixtures by plasma-polymerized membranes from silicone compounds",J.Membr.Sci.,36,353-362(1988).
28 Matsuda,H.,Yanagishita,H.,Negishi,H.,Kitamoto,D.,Ikegami,T.,Haraya,K.,Nakane,T.,Idemoto,Y.,Koura,N.,Sano,T.,"Improvement of ethanol selectivity of silicalite membrane in pervaporation by silicone rubber coating",J.Membr.Sci.,210,433-437 (2002).
29 Guo,J.,Zhang,G.,Wu,W.,Ji,S.,Qin,Z.,Liu,Z.,"Dynamically formed inner skin hollow fiber polydimethylsiloxane/polysulfone composite membrane for alcohol permselective pervaporation",Chem.Eng.J.,158,558-565(2010).
30 Li,L.,Xiao,Z.,Tan,S.,Pu,L.,Zhang,Z.,"Composite PDMS membrane with high flux for the separation of organics from water by pervaporation",J.Membr.Sci.,243,177-187(2004).
31 Hennepe,H.J.C.,Bargeman,D.,Mulder,M.H.V.,Smolders,C.A.,"Zeolite-filled silicone rubber membranes.Part 1.Membrane preparation and pervaporation results",J.Membr.Sci.,35,39-55(1987).
32 Jia,M.,Pleinemann,K.,Behling,R.,"Preparation and characterization of thin-film zeolite-PDMS composite membranes",J.Membr. Sci.,73,119-128(1992).
33 Vankelecom,I.F.J.,Depre,D.,Beukelaer,S.De,Uytterhoeven,J.B.,"Influence of zeolites in PDMS membranes.Pervaporation of water/alcohol mixtures",J.Phys.Chem.,99,13193-13197(1995).
34 Yi,S.L.,Su,Y.,Wan,Y.H.,"Preparation and characterization of vinyltriethoxysilane(VTES)modified silicalite-1/PDMS hybrid pervaporation membrane and its application in ethanol separation from dilute aqueous solution",J.Membr.Sci.,360,341-351(2010).
35 Vane,L.M.,Namboodiri,V.V.,Bowen,T.C.,"Hydrophobic zeolite-silicone rubber mixed matrix membranes for ethanol-water separation:effect of zeolite and silicone component selection on pervaporation performance",J.Membr.Sci.,308,230-241(2008).
36 Zhan,X.,Li,J.D.,Chen,J.,Huang,J.Q.,"Pervaporation of ethanol/water mixtures with high flux by zeolite-filled PDMS/PVDF composite membranes",Chin.J.Polym.Sci.,27,771-780(2009).
37 Jonquieres,A.,Fane,A.,"Filled and unfilled composite GFT PDMS membranes for the recovery of butanols from dilute aqueous solutions:influence of alcohol polarity",J.Membr.Sci.,125,245-255 (1997).
38 Huang,J.C.,Meagher,M.M.,"Pervaporative recovery of n-butanol from aqueous solutions and ABE fermentation broth using thin-film silicalite-filled silicone composite membranes",J.Membr.Sci.,192,231-242(2001).
39 Liu,F.F.,Liu,L.,Feng,X.S.,"Separation of acetone-butanol-ethanol (ABE)from dilute aqueous solutions by pervaporation",Sep.Purif. Technol.,42,273-282(2005).
40 Liu,X.L.,Li,Y.S.,Liu,Y.,Zhu,G.Q.,Liu,J.,Yang,W.S.,"Capillary supported ultrathin homogeneous silicalite-poly(dimethylsiloxane) nanocomposite membrane for bio-butanol recovery",J.Membr.Sci.,369,228-232(2011).
41 Qureshi,N.,Blaschek,H.P.,"Production of acetone butanol ethanol (ABE)by a hyper-producing mutant strain of Clostridium beijerinckii BA101 and recovery by pervaporation",Biotechnol.Progr.,15,594-602(1999).
42 Qureshi,N.,Maddox,I.S.,Friedl,A.,"Application of continuous substrate feeding to the ABE fermentation:relief of product inhibition using extraction,perstraction,stripping,and pervaporation",Biotechnol.Progr.,8,382-390(1992).
[43] Chen,J.,Li,J.D.,Chen,J.X.,Lin,Y.Z.,Wang,X.G.,"Pervaporation separation of ethyl thioether/heptane mixtures by polyethylene glycol membranes",Sep.Purif.Technol.,66,606-612(2009).
[44] Li,B.,Xu,D.,Jiang,Z.Y.,Zhang,X.F.,Liu,W.P.,Dong,X.,"Pervaporation performance of PDMS-Ni²⁺ Y zeolite hybridmembranes in the desulfurization of gasoline",J.Membr.Sci.,322,293-301 (2008).
[45] Zhao,C.W.,Li,J.D.,Qi,R.B.,Chen,J.,Luan,Z.K.,"Pervaporation separation of n-heptane/sulfur species mixtures with polydimethylsiloxane membranes",Sep.Purif.Technol.,63,220-225(2008).
[46] Devi,D.A.,Raju,K.V.S.N.,Aminabhavi,T.M.,"Synthesis and characterization of moisture-cured polyurethane membranes and their applications in pervaporation separation of ethyl acetate/water azeotrope at 30°C",J.Appl.Polym.Sci.,103,3405-3414(2007).
[47] Salt,Y.,Hasanoglu,A.,Salt,I.,Keleser,S.,Dincer,S.O.S.,"Pervaporation separation of ethylacetate-water mixtures through a crosslinked poly(vinylalcohol)membrane",Vacuum,79,215-220 (2005).
[48] Yuan,H.K.,Xu,Z.L.,Shi,J.H.,Ma,X.H.,"Perfluorosulfonic acid-tetraethoxysilane/polyacrylonitrile(PFSA-TEOS/PAN)hollow fiber composite membranes prepared for pervaporation dehydration of ethyl acetate-water solutions",J.Appl.Polym.Sci.,109,4025-4035(2008).
[49] Morigami,Y.,Kondo,M.,Abe,J.,Kita,H.,Okamoto,K.,"The first large-scale pervaporation plant using tubular-type module with zeolite NaA membrane",Sep.Purif.Technol.,25,251-260(2001).
[50] O'Brien,D.J.,Roth,L.H.,McAloon,A.J.,"Ethanol production by continuous fermentation-pervaporation:A preliminary economic analysis",J.Membr.Sci.,166,105-111(2000).
[51] Vane,L.M.,"A review of pervaporation for product recovery from biomass fermentation processes",J.Chem.Technol.Biotechnol.,80,603-629(2005).
[52] Xu,L.F.,Xiangli,F.J.,Chen,Y.W.,Jin,W.Q.,Xu,N.P.,"Progress in pervaporation for biofuel ethanol",Chem.Ind.Eng.Prog.(China),26,788-796(2007).(in Chinese)
[53] Jin,W.Q.,Liu,G.P.,Xu,N.P.,"Progress of pervaporation in bio-butanol production from ABE fermentation",Membr.Sci.Technol.(China),31,25-31(2011).(in Chinese)
[54] White,L.S.,Wormsbecher,R.F.,Lesemann,M.,"Membrane separation for sulfur reduction",U.S.Pat.,6896796(2005).

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