Manipulation of confined structure in alcohol-permselective pervaporation membranes

doi:10.1016/j.cjche.2017.05.004

Chinese Journal of Chemical Engineering ›› 2017, Vol. 25 ›› Issue (11): 1616-1626.DOI: 10.1016/j.cjche.2017.05.004

Manipulation of confined structure in alcohol-permselective pervaporation membranes

Jing Zhao, Wanqin Jin

State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, Nanjing 210009, China

收稿日期:2016-12-14 修回日期:2017-05-14 出版日期:2017-11-28 发布日期:2018-01-18
通讯作者: Wanqin Jin,E-mail address:wqjin@njtech.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China (21490585, 21606123), the Jiangsu Province Natural Science Foundation for the Youth (BK20160980), the Innovative Research Team Program by the Ministry of Education of China (IRT13070), Top-notch Academic Programs Project of Jiangsu Higher Education Institutions (TAPP) and A Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

Manipulation of confined structure in alcohol-permselective pervaporation membranes

Jing Zhao, Wanqin Jin

State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, Nanjing 210009, China

Received:2016-12-14 Revised:2017-05-14 Online:2017-11-28 Published:2018-01-18
Contact: Wanqin Jin,E-mail address:wqjin@njtech.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China (21490585, 21606123), the Jiangsu Province Natural Science Foundation for the Youth (BK20160980), the Innovative Research Team Program by the Ministry of Education of China (IRT13070), Top-notch Academic Programs Project of Jiangsu Higher Education Institutions (TAPP) and A Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

摘要/Abstract

摘要： Alcohol-permselectivity pervaporation has been arousing increasingly more attention in bioalcohol production due to the advantages of environmental friendliness, low energy consumption and easy coupling with fermentation process. With the intrinsic feature of larger molecules preferentially permeating and the consequent inferiority in selective diffusion, the development of alcohol-permselective membrane is relatively retarded compared with water-permselective membrane. This review presents the prevalent membrane materials utilized for alcohol-permselective pervaporation and emphatically expatiates the representative and important developments in the past five years from the aspect of tuning confined structure in membranes. In particular, the diverse structure tuning methods are described with the classifications of physical structure and chemical structure. The corresponding structure-performance relationships in alcohol-permselective pervaporation membranes are also analyzed to identify the objective of structure optimization. Furthermore, the tentative perspective on the possible future directions of alcohol-permselective pervaporation membrane is briefly presented.

关键词: Confined structure, Pervaporation, Membrane, Alcohol-permselective

Abstract: Alcohol-permselectivity pervaporation has been arousing increasingly more attention in bioalcohol production due to the advantages of environmental friendliness, low energy consumption and easy coupling with fermentation process. With the intrinsic feature of larger molecules preferentially permeating and the consequent inferiority in selective diffusion, the development of alcohol-permselective membrane is relatively retarded compared with water-permselective membrane. This review presents the prevalent membrane materials utilized for alcohol-permselective pervaporation and emphatically expatiates the representative and important developments in the past five years from the aspect of tuning confined structure in membranes. In particular, the diverse structure tuning methods are described with the classifications of physical structure and chemical structure. The corresponding structure-performance relationships in alcohol-permselective pervaporation membranes are also analyzed to identify the objective of structure optimization. Furthermore, the tentative perspective on the possible future directions of alcohol-permselective pervaporation membrane is briefly presented.

Key words: Confined structure, Pervaporation, Membrane, Alcohol-permselective

Jing Zhao, Wanqin Jin. Manipulation of confined structure in alcohol-permselective pervaporation membranes[J]. Chinese Journal of Chemical Engineering, 2017, 25(11): 1616-1626.

Jing Zhao, Wanqin Jin. Manipulation of confined structure in alcohol-permselective pervaporation membranes[J]. Chin.J.Chem.Eng., 2017, 25(11): 1616-1626.

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Manipulation of confined structure in alcohol-permselective pervaporation membranes

Manipulation of confined structure in alcohol-permselective pervaporation membranes

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